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Bloodlusted Hancock doesn't fuck around with Lust Mero Beams. She fires slave arrows at him until he comes closer to cut off her range advantage, and she kicks his face off. Mid/High diff, based on revelations of her actual reaction speed when not playing "Archer".
Current Luffy is pretty fast, but Hancock's Slave Arrow is too. Besides, there are too many of them so there are big chances he could get hurt before he gets closer to her and since the attack has nothing to do with lust, it's pretty obvious that he would definitely have some trouble.
If that doesn't work ( which could, considering Luffy's impressive speed and reactions ), she just has to come closer to him at full speed and kick him with Perfume Femur to a dangerous spot ( head or arms ).
Luffy could try to hit her and that could actually work, but I'm taking in account that she could easily petrify "anyone" so if she hits him, he'll lose.
She takes this with mid difficulty, in my opinion.